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Manifestation of charge-density fluctuations in metal clusters: Suppression of the ionization channel

Kidun, O., Berakdar, J.

Physical Review Letters 87, pp 263401 (2001)

The fluctuations in the electronic charge density of metallic clusters in response to an approaching electron suppress the single-ionization channel. This conclusion is made on the basis of numerical calculations for the total ionization cross sections using the random-phase approximation with exchange to describe the particle-hole (de)excitations. The general trends can be understood by means of the Thomas-Fermi model. The present theory explains, for the first time, the behavior of the measured total ionization cross section for C60. The interplay between finite size and nonlocal screening effects is studied by tracing the changes in the ionization cross sections for Li clusters with an increasing cluster radius.

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